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Composition of Concrete


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Composition of Concrete

There are many types of concrete available, created by varying the proportions of the main ingredients below. By varying the proportions of materials, or by substitution for the cemetitious and aggregate phases, the finished product can be tailored to its application with varying strength, density, or chemical and thermal resistance properties.The mix design depends on the type of structure being built, how the concrete will be mixed and delivered, and how it will be placed to form this structure.

Cement

Portland cement is the most common type of cement in general usage. It is a basic ingredient of concrete, mortar, and plaster. English masonry worker Joseph Aspdin patented Portland cement in 1824; it was named because of its similarity in colour to Portland limestone, quarried from the English Isle of Portland and used extensively in London architecture. It consists of a mixture of oxides of calcium, silicon and aluminium. Portland cement and similar materials are made by heating limestone (a source of calcium) with clay, and grinding this product (called clinker) with a source of sulfate (most commonly gypsum).

Water

Combining water with a cementitious material forms a cement paste by the process of hydration. The cement paste glues the aggregate together, fills voids within it, and allows it to flow more freely. Less water in the cement paste will yield a stronger, more durable concrete; more water will give an freer-flowing concrete with a higher slump.Impure water used to make concrete can cause problems when setting or in causing premature failure of the structure.

Hydration involves many different reactions, often occurring at the same time. As the reactions proceed, the products of the cement hydration process gradually bond together the individual sand and gravel particles, and other components of the concrete, to form a solid mass.

Aggregates

Fine and coarse aggregates make up the bulk of a concrete mixture. Sand, natural gravel and crushed stone are mainly used for this purpose. Recycled aggregates (from construction, demolition and excavation waste) are increasingly used as partial replacements of natural aggregates, while a number of manufactured aggregates, including air-cooled blast furnace slag and bottom ash are also permitted.

Aggregates

Decorative stones such as quartzite, small river stones or crushed glass are sometimes added to the surface of concrete for a decorative "exposed aggregate" finish, popular among landscape designers.The presence of aggregate greatly increases the robustness of concrete over and above that of cement, which otherwise is a brittle material, and thus concrete is a true composite material.

Redistribution of aggregates after compaction often creates inhomogeneity due to the influence of vibration. As a result, gradients of strength may be significant.Installing rebar in a floor slab during a concrete pour.

Reinforcement

Concrete is strong in compression, as the aggregate efficiently carries the compression load. However, it is weak in tension as the cement holding the aggregate in place can crack, allowing the structure to fail. Reinforced concrete solves these problems by adding either steel reinforcing bars, steel fibers, glass fiber, or plastic fiber to carry tensile loads. Thereafter the concrete is reinforced to withstand the tensile loads upon it.

Chemical admixtures

Chemical admixtures are materials in the form of powder or fluids that are added to the concrete to give it certain characteristics not obtainable with plain concrete mixes. In normal use, admixture dosages are less than 5% by mass of cement, and are added to the concrete at the time of batching/mixing. The common types of admixtures are as follows.
* Accelerators speed up the hydration (hardening) of the concrete. Typical materials used are CaCl2 and NaCl. However, use of chlorides may cause corrosion in steel reinforcing and is prohibited in some countries.

* Retarders slow the hydration of concrete, and are used in large or difficult pours where partial setting before the pour is complete is undesirable. Typical polyol retarders are sugar, sucrose, sodium gluconate, glucose, citric acid, and tartaric acid.

* Air entrainments add and entrain tiny air bubbles in the concrete, which will reduce damage during freeze-thaw cycles thereby increasing the concrete's durability. However, entrained air is a trade-off with strength, as each 1% of air may result in 5% decrease in compressive strength.

Chemical admixtures

* Plasticizers increase the workability of plastic or "fresh" concrete, allowing it be placed more easily, with less consolidating effort. Typical plasticizers are lignosulfonate. Plasticizers can be used to reduce the water content of a concrete while maintaining workability, and are sometimes called water-reducers due to this use. Such treatment improves its strength and durability characteristics. Superplasticizers (also called high-range water-reducers) are a class of plasticizers that have fewer deleterious effects, and can be used to increase workability more than practical with traditional plasticizers. Compounds used as superplasticizers include sulfonated naphthalene formaldehyde condensate, sulfonated melamine formaldehyde condensate, acetone formaldehyde condensate, and polycarboxylate ethers.

* Pigments can be used to change the color of concrete, for aesthetics.

* Corrosion inhibitors are used to minimize the corrosion of steel and steel bars in concrete.

* Bonding agents are used to create a bond between old and new concrete.

* Pumping aids improve pumpability, thicken the paste, and reduce separation and bleeding.

Mineral admixtures and blended cements

There are inorganic materials that also have pozzolanic or latent hydraulic properties. These very fine-grained materials are added to the concrete mix to improve the properties of concrete (mineral admixtures), or as a replacement for Portland cement (blended cements).
* Fly ash: A by product of coal fired electric generating plants, it is used to partially replace Portland cement (by up to 60% by mass). The properties of fly ash depend on the type of coal burnt. In general, silicious fly ash is pozzolanic, while calcareous fly ash has latent hydraulic properties.

* Ground granulated blast furnace slag (GGBFS or GGBS): A by-product of steel production is used to partially replace Portland cement (by up to 80% by mass). It has latent hydraulic properties.

silica fume

* Silica fume: A by-product of the production of silicon and ferrosilicon alloys. Silica fume is similar to fly ash, but has a particle size 100 times smaller. This results in a higher surface to volume ratio and a much faster pozzolanic reaction. Silica fume is used to increase strength and durability of concrete, but generally requires the use of superplasticizers for workability.

* High reactivity Metakaolin (HRM): Metakaolin produces concrete with strength and durability similar to concrete made with silica fume. While silica fume is usually dark gray or black in color, high reactivity metakaolin is usually bright white in color, making it the preferred choice for architectural concrete where appearance is important.



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